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Beilstein J. Org. Chem. 2011, 7, 1036–1045, doi:10.3762/bjoc.7.118
Graphical Abstract
Scheme 1: Synthesis of anthracene oxides.
Scheme 2: Synthesis of methoxyanthracenes 10 and 11.
Figure 1: Molecular structure of compound 7. Displacement ellipsoids are shown at 40% probability level.
Scheme 3: The reaction mechanism for the formation of methoxyanthracenes 10 and 11.
Scheme 4: The formation mechanism for dihydroxy 17.
Figure 2: a) X-ray ORTEP plot of compound 17. Displacement ellipsoids are shown at 40% probability level. b) ...
Scheme 5: Base-promoted reaction of the dihydroxides and formation of the epoxides.
Scheme 6: Synthesis of compounds 27 and 28.
Beilstein J. Org. Chem. 2008, 4, No. 50, doi:10.3762/bjoc.4.50
Scheme 1: Photobromination of 9,10-dibromoanthracene.
Figure 1: ORTEP view of hexabromide 5.
Scheme 2: Configuration isomerization mechanism of the hexabromides.
Scheme 3: Dehydrobromination of hexabromide 3 with various bases. Relative percentages were calculated by int...
Scheme 4: Preparation of trisubstituted anthracene derivatives.